I'm one of the people who found 4E to be better than 3.P for my taste and the need of my group. I have an open mind for improvised rituals and my campaign tends to be plot oriented enough that most of the unfortunate 4E baggage can be ignored, and I loved the freshness of the combat system (at least for martial types) and the generic flavor that could easily be retooled. However, that group is no more and what's left of it is now bored to death from the combat system of 4E. So it seems I have to run a 3.P campaign now.
Back in the day we had plenty of optimization problems. However I read enough and suffered enough to know what to look for. I chopped down the class system to tiny pieces and left something that shouldn't give too much trouble, and most importantly my players are mature. So I'm not too scared of intra-party balance.
What I'm scared of, is the CR system. I come from years and years of "throw something together in under a minute, add some interesting terrain et voilĂ the encounter is ready". I come from years of expecting to know what makes for a tough fight and what is a cakewalk that plays into the party's strength. I have no expectations to be able to be quite as accurate in my predictions, because the system is completely different; however I want all the advice you can give on how to prepare for this campaign. The group is going to be Tier 3 and moderately-to-well optimized. We are going to be running from level 5 to I think level 15-ish. Pathfinder and 3.5 material is all open, but with unlimited bans on my part (I reserve the right to sniff out cheese and kill it with no save allowed). How do I challenge these guys, and how do I make sure the fights I prepare are at the opportune difficulty level?
(Also, please don't say "run through the fight a couple times". I don't have that much time to prepare. I want to be able to throw an encounter together during the session if need be, because I usually don't know what's going to happen in game. I will be able to prepare "random" fights beforehand and adapt them on the fly, but I still want to spend as little time as possible on that stuff)
EDIT: also yeah I don't know where I should post this. I figure this is probably the place but I've been wrong in the past.