It depends on the type of rogue you want to make. If social, Tempest Stormwind recently made a gorgeous build on the WotC forum. If dungeon-crawling, Slayer is really all you need, the right power selection will solve most of the problems for you. For DPR, the psion has the rogue beat, but, for precision damage, beyond just going Martial Stance:Assassin's Stance at level 12? I got nothing. For damage, an egotist, or just any psion with the right powers should outdo any rogue.
How are you handling Perils? And might I point you at Dark Heresy. It sounds like it's got everything your DM wants, but better.