I've always been fond of the Jovoc's (MMII) retributive aura.
The Ethereal Defiler (MMV) can shoot a 6d6 eldritch blast as a swift action every round, stacks with any warlock levels. Not super powerful, but always seemed kind of fun. Actually gives a monster something to do with its swift actions for once.
Blink Dog's free action dimension door, and you can still act afterwards, is pretty awesome to keep your monster mobile.
The yugoloth in MMIV, Corruptor of Fate, has an awesome ability that makes anyone attacking it roll twice for the hit and twice for damage. Your foe HAS to take the lower roll.